I'd pretend that a 100' hose can reach 90', otherwise you're going to be putting a lot of tension on your hose bibs and always having to tug on the hose to get the final few feet to get to your spot.
I personally like the idea of the spigots on the perimeter, because there's likely a fence there and it helps guard the spigot (and possibly give you something to brace it to). If you're set on doing this, I'd put one at the middle of each end, and then one every 82' on the sides (at 82, 164, 246, 328, 410). This would give full coverage with a bit of overlap where you could manage to reach spots near the end of the hose with two or three different bibs. It would suck to be wanting to use water in a medium size area and have to pull hoses from three different bibs to get it all when an extra bib or two could've allowed a bit more overlap; more bibs would increase the chance that a single hose lay would hit everything you're doing in one area.
Overall I have to say it's better to have an idea of where you actually want to be using the water rather than trying to cover the whole area. Why? Because you're likely to find in the future that you don't actually want to be dealing with 100' hoses all the time, and you may prefer to have a spigot *right there* so that you can do a variety of chores there with one or more shorter hoses. So, either bite the bullet now and run an extra 50% bibs (I doubt you'll regret it) or just run a few, get extra hose, and live with inconvenience for a couple of years and see how you're actually using the land.
I've literally moved a hose bib 12' because I didn't like where it was before (ain't it nice having a digger?).
I've taken to setting a cross tee (like a tee, but it's got four connections instead of three) on top of my pipes, with three hose bibs coming off the cross - one 3/4" on top and two 1/2" on the sides, which gives me great flexibility with a more reliable valve than temporary Y's when I want to hook up more than one hose or water use at a bib (typically I use a side spigot for an irrigation sprinkler timer, and keep the top valve available for more various hose uses; very rarely I use all three but it's nice not having to go find a Y when I do).