The outlet from the loader valve (open center, no power beyond) is all flow IF nothing is plumbed after the loader valve. If you plumb the backhoe in series after the loader valve in the loader valve outlet line you will be able to operate the backhoe if the loader isn't being used at the same time. However you will be restricting the flow through the loader valve because your backhoe valve is only rated at 14 gpm. That's all the flow you'll get through the loader valve even if the backhoe isn't being used.