Given a fixed volume (size dimensions) Which battery Voltage provides the most available energy (Ah) ? I'm talking about small batteries as might be fitted to a TRACTOR. ;-)
I know that energy terms can be confusing, but Ah is current, and Ah times voltage (VA / Watt, power), and power times time is energy.
I'm not sure that amp-hours alone is the right metric, as what is needed is power, or total energy for multiple starts.
For most tractors, the reason the battery is there to get the tractor started, and what is needed is (cold) cranking amps (CCA) /CA, at a given voltage. Batteries with large plate area, and therefore a low internal resistance tend to have the best CA, such as an AGM starting battery. In principle, a lithium battery would do even better, but most are not constructed to support the high starting currents needed for an engine starter. Even better is an ultra capacitor, but you do not get that many attempts at starting with capacitor as the stored energy is low compared to a battery.
If you double the voltage, you need half the cranking amps, and the effects of clean battery terminals and good grounds become less important, though still important. You do get to save on wire size, which is why newer cars are tending to a 48V standard.
There are even pony motors, hydraulic starters, compressed air starters, or even mechanical spring starters, but that's not exactly your question...
@CalG does that help at all?
All the best,
Peter