Expansion valves are pretty bullet proof - unless the compressor grenades and fills the system with debris (aka Black Death). But then you have a total system rebuild. Since yours blows nice and cold when working, that isn't it.
Not sure what they mean by Tstat - is there one on the evap or in the cabin for the HVAC? Obviously it is not the engine Tstat...
Checking for voltage at the clutch would be wise. If you don't see it when it should be engaged, then odds are it's electrical. In fact, as I look back through the thread, here's the key from an earlier post of yours:
10:35.........104.....105.......zero volts at clutch, still no compressor op
Zero volts at clutch means the system is not telling the coil to energize. The electricals are really butt-simple here. Selector switch to LP & HP sensor and maybe some tie-in to an engine computer. Work your way back from the clutch and forward from the switch. Look for voltage at any connection you can find and wiggle wires and connectors. It might just be a bad connection or internally broken wire in the wiring loom. This is where jumpering the LP switch is often done to see if the LP switch is bad.
The "dual type switch" I think is just lousy Japanese translation. I believe they just mean it has both LP & HP switches, which is typical.
Now as for letting freon out. You will have to let it out via the gage set, but you need to be REALLY CAREFUL here as any freon contact with skin can/will cause near instant frostbite. Long sleeves, gloves, safety glasses and some way to activate the outlet like a screwdriver tip. That will depend on how your gage set operates for how you can let it escape. System off and stabilized at ambient pressure too. You will have to blow out a lot to get rid of a full can that you added...The system may only take 2 or 3 cans for full charge and you added one more to that. That's a large percentage of the total charge. The other way to deal with this is to have the tech hook it up to a recovery machine, suck it all out, vacuum the system down and then add back the correct amount. If you have a guy coming, you may want to let him do it that way.